№6|2022
WASTE MANAGEMENT
DOI 10.35776/VST.2022.06.07
UDC 628.544:54-414
Magnetic sorbents from galvanic sludge for oily wastewater treatment
Summary
The results of studying the properties of sorbents prepared from galvanic sludge in relation to oil products are presented. For the synthesis, the method of solution combustion synthesis was chosen. Glycine was used as a reducing agent in a stoichiometric ratio with the oxidizing agent. X-ray phase analysis of the obtained samples showed that they contained iron mainly in the form of a magnetite phase. The total static exchange capacity and specific surface area of the synthesized sorbent samples (up to 130 m2/g) were determined from the sorption of the methylene blue dye. The oil capacity of the obtained materials (up to 3 g/g) is not inferior to the natural sorbents of oil products. Preparing magnetic oil sorbents is possible by the combined use of waste iron and nickel-containing galvanic sludges resulting in the reduction of the negative anthropogenic impact on the environment and elimination of the expensive technologies.
Key words
oil products , wastewater treatment , sorbent , exothermic combustion in solutions , galvanic sludges
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Список цитируемой литературы
- Dolbnia I. V. Razrabotka magnitnykh kompozitsionnykh sorbentov na osnove gal’vanoshlama dlia ochistki vody ot nefteproduktov i ionov tiazhelykh metallov [Development of magnetic composite sorbents based on galvanic sludge for removing oil products and heavy metal ions from water. Synopsis of a thesis for Ph. D. degree in Engineering. Saratov, 2018, 155 p.].
- Privalova N. M., Dvadnenko M. V., Nekrasova A. A., Popova O. S., Privalov D. M. [Oily wastewater treatment with the use natural and artificial sorbents]. Politematicheskii Setevoi Elektronnyi Nauchnyi Zhurnal Kubanskogo Gosudarstvennogo Agrarnogo Universiteta, 2015, no. 113, pp. 297–306. (In Russian).
- Pashchevskaia N. V. [Methods and means of reducing the ecological burden on the environment]. Chrezvychainye Situatsii: Promyshlennaia i Ekologicheskaia Bezopasnost’, 2018, no. 2, pp. 83–89. (In Russian).
- Nurullaev Sh. P., Ruzmatov I., Saidmirzaeva D. B. [Sorption materials using rotary slags and their application for water treatment]. Universum: Tekhnicheskie Nauki, 2020, no. 2–2 (71), pp. 64–67. (In Russian).
- Gorelaia O. N., Romanovski V. I. [Magnetic sorbent from water treatment sludge for oily wastewater treatment.]. Vestnik Brestskogo Gosudarstvennogo Tekhnicheskogo Universiteta. Water Engineering, Thermal Power Engineering and Geoecology, 2020, no. 2, pp. 61–64. (In Russian).
- Romanovski V. I., Gorelaia O. N., Khort A. A. [Magnetic sorbents for the removal of oil products from water media]. Topical issues and prospects for the development of transport and construction complexes: Proceedings of the IV International Scientific and Practical Conference. Part 1. Gomel, BelGUT Publ., 2018, pp. 215–216. (In Russian).
- Martsul’ V. N., Likhacheva A. V., Zalygina O. S., Shibeka L. A., Romanovski V. I. [Elemental and phase composition of galvanic sludges, sludges of machine-building and instrument-making enterprise wastewater treatment facilities of the Republic of Belarus]. Prirodnye Resursy, 2013, no. 1, pp. 113–118. (In Russian).
- Martsul’ V. N., Zalygina O. S., Shibeka L. A., Likhacheva A. V., Romanovski V. I. [Some areas of use of galvanic production waste]. Writings of BGTU. Chemistry and Technology of Inorganic Substances, 2012, no. 3 (150), pp. 70–75. (In Russian).
- Martsul’ V. N., Zalygina O. S., Shibeka L. A., Likhacheva A. V., Romanovski V. I., Khodin V. V. [Inventory of galvanic sludge and sludge from the local industrial wastewater treatment facilities in the Republic of Belarus]. Writings of BGTU. Chemistry and Technology of Inorganic Substances, 2012, no. 3 (150), pp. 76–83. (In Russian).
- Martsul’ V. N., Zalygina O. S., Likhacheva A. V., Romanovski V. I. [Wastewater treatment of electroplating shops of enterprises of the Republic of Belarus]. Writings of BGTU. Chemistry and Technology of Inorganic Substances, 2013, no. 3 (159), pp. 61–66. (In Russian).
- Osinin M. S., Romanovski V. I., Likhavitskii V. V., Romanovskaia E. V. [Acid leaching of iron from sludges of natural water coagulation]. Vestnik BrGTU. Water Engineering, Thermal Power Engineering and Geoecology, 2019, no. 2, pp. 50–52. (In Russian).
- Kulichik D. M., Romanovski V. I., Likhavitskii V. V. [Acid leaching of iron from iron-containing sludges of de-ironing plants]. Vestnik BrGTU. Water Engineering, Thermal Power Engineering and Geoecology, 2019, no. 2, pp. 52–54. (In Russian).
- Gorelaia O. N., Romanovski V. I. [Sorbent for oily wastewater treatment based on the wastes of de-ironing plants]. Vodosnabzhenie i Sanitarnaia Tekhnika, 2020, no. 10, pp. 48–54. (In Russian).
- Romanovski V. I., Kulichik D. M., Pilipenko M. V., Romanovskaia E. V. [Iron-containing photocatalysts based on the sludge of de-ironing filter wash water]. Vodoochistka. Vodopodgotovka. Vodosnabzhenie, 2019, no. 4, pp. 18–22. (In Russian).
- Gorelaia O. N., Budeiko N. L., Romanovski V. I. [Magnetic sorbent based on water treatment sludge for the removal of oil products from water media]. Vestnik Polotskogo Gosudarstvennogo Universiteta. Series F. Construction. Applied Science, 2020, no. 16, pp. 52–57. (In Russian).
- Gorelaia O. N., Romanovski V. I. [Effect of the dose of the reducing agent on the properties of magnetic sorbents from de-ironing plant wastes]. Vodosnabzhenie i Sanitarnaia Tekhnika, 2022, no. 1, pp. 32–37. (In Russian).
- Kamenshchikov F. A., Bodomol’nyi E. I. Neftianye sorbenty [Oil sorbents. Moscow-Izhevsk, SRC «Reguliarnaia i Khaoticheskaia Dinamika» Publ., 2005, 268 p.].
- Lukashevich O. D., Usova N. T. [Sorbent from ferriferous sludge for the removal of heavy metal ions from wastewater]. Vestnik Tomskogo Gosudarstvennogo Arkhitekturno-Stroitel’nogo Universiteta, 2018, v. 20, no. 1, pp. 148–159. (In Russian).
- Nikolaeva L. A., Khamzina D. A. [Study of chemical water treatment sludge as an oil sorbent in the purification of water bodies]. Vestnik Tekhnologicheskogo Universiteta, 2018, v. 21, no. 2, pp. 200–204. (In Russian).
- Pernyeszi T., Farkas R., Kovács J. Methylene blue adsorption study on microcline particles in the function of particle size range and temperature. Minerals, 2019, v. 9, no. 9, p. 555.
- Aringhieri R., et al. Testing a simple methylene blue method for surface area estimation in soils. AGROCHIMICA-PISA, 1992, v. 36, pp. 224–224.
- Teas C., Kalligeros S., Zanikos F., Stoumas S., Lois E., Anastopoulos G. Investigation of the effectiveness of absorbent materials in oil spills clean-up. Desalination, 2001, v. 140, no. 3, pp. 259–264.
- Baiburdov T. A., Shmakov S. L. [Polymeric sorbents for collecting oil products from the surface of water bodies: a review of the English-language literature for 2000–2017 (part 2)]. Izvestiia Saratovskogo Universiteta. New Series. Series Chemistry. Biology. Ecology, 2018, v. 18, no. 2, pp. 145–153. (In Russian).
- Grinshpan D. D., Telysheva G. M., Neavar T. N., Dizhbit T. N., Tsygankova N. G., Arshanitsa A. S., Golovko A. S., Solodovnik V. P. [Oil sorbent based on hydrolytic lignin]. Vestnik NAN Belarusi. Chemical Sciences Series, 2011, no. 2, pp. 23–28. (In Russian).