DOI 10.35776/VST.2021.07.01
UDC 628.16.081
Seliukov Aleksandr
Integrated technology for conditioning low-mineralized cold ground water
Summary
An advanced integrated technology for conditioning low-mineralized cold groundwater is presented. The technology was developed for the purpose of supplying drinking water to the oil and gas-bearing regions of the Tyumen North. With a favorable ratio of fresh water resources and the actual volume of water consumption in this region of Russia, the issue of drinking water supply from underground aquifers remains acute due to the problematic water quality and low efficiency of the treatment facilities. The technology is intended for removing iron, manganese, hydrogen sulfide and providing for the stabilization treatment of water. The main work including laboratory studies and pilot tests was carried out in the period 2001–2020. On the basis of the developed process solutions, water treatment facilities have been built and successfully operated in the cities of Noyabrsk (75 thousand m3/day, 2006) and Novy Urengoy (65 thousand m3/day, 2007). Additional tests of the technology carried out in Khanty-Mansiisk and Komsomolsk-on-Amur confirmed its effectiveness. The technology involves using hydrogen peroxide and potassium permanganate as the basic chemicals for the oxidation of water pollutants, as well as using an alkaline chemical for pH adjustment and stabilization treatment. To meet the requirements of the WHO standard for the concentrations of iron and manganese, an additional flocculant can be used. The data on the composition of groundwater used for testing are summarized, and on their basis the recommended area of application of the developed technology is determined. The basic process flow scheme of conditioning low-mineralized cold groundwater in view of 15 years of experience in operating the existing facilities, and of advanced solutions for dosing and mixing of chemicals, is presented. It is indicated that the technology also provides for a partial reduction in the silicon concentration in purified water (up to 30%). The developed technology ensures stable drinking water with a standard residual concentration of iron, manganese and hydrogen sulfide.
Key words
deferrization , hydrogen peroxide , ground water , potassium permanganate , demanganization , stabilization treatment , caustic soda , hydrogen sulfide removal
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UDC 628.161.2:546.72/.711
Seliukov Aleksandr, Baikova Ida
Underground water conditioning for utility and drinking water supply of oil refinery producing area
Summary
The results of experimental studies of conditioning underground water containing high iron concentrations for utility and drinking water supply of oil refinery producing area are presented. At the first stage the exact values of underground water pH and redox potential of the medium were defined in order to evaluate the potential of using different deironing-demanganation processes. A specially designed flow-through temperature-controlled cell was used for measurements. The comprehensive technology of chemical treatment developed earlier for conditioning underground water at the Tumen North here again ensures the standard quality of drinking water. In the process of removing iron and manganese from water with simultaneous stabilization the chemicals having RF certificates for drinking water supply are used: hydrogen peroxide (GOST 177-88), potassium permanganate (ANSI/AWWA 603-88 standard) and caustic soda (GB 5175-2008 standard). The use of stabilization treatment provides for the elimination of secondary pollution with iron in the distribution network. Separation of insoluble reaction products was carried out by filtration through granular bed (quartz sand of 0.5–1.2 mm fraction). The obtained correlations between redox potential and chemical dosages allow to automatize the dosing process. In this case the technology provides for the residual concentration of iron and manganese less than 0.1 mg/l in drinking water. As an additional effect the technology ensures reducing the concentration of pollutants of technogenic origin– anionic surfactants (75%) and oil products (90%). Thereby the residual concentration meets the standard for bottled water. On the basis of the carried out tests the Process regulations for designing facilities for underground water conditioning of 4800 m3/day capacity were developed.
Key words
deferrization , ground water , demanganization , stabilization treatment , removal of technogenic pollutants
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UDC 628.161.2:546.72/.711
Seliukov Aleksandr, Baikova Ida, Solovyova O. V.
Conditioning underground water of the Amur water intake (the city of Komsomolsk-on-Amur)
Summary
The results of investigating conditioning underground water of the Amur water intake of Komsomolsk-on-Amur are given. At present the construction of in situ deironing-demanganation facilities is underway; however the test operation of the first stage showed that the water quality did not meet the normative standard. An alternative technology was suggested, i.e. chemical treatment that ensured water stabilization and elimination of iron and manganese. In-process tests take into account all possible scenarios of operating the integrated aquifer treatment facilities under construction.
Key words
deferrization , ground water , demanganization , stabilization treatment
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DOI 10.35776/VST.2022.04.02
UDC 628.161.3:628.168.3
Seliukov Aleksandr, Raff P. A., Mishina T. F.
Pre-project in-process testing river water purification in the Arctic Circle
Summary
The results of pre-project in-process testing purification of water of the Vary-Khadyta River, the source of drinking and domestic water supply for the village of Yar-Sale (Yamal-Nenets Autonomous Okrug), are presented. Throughout the year the permissible concentration of iron, manganese, suspended solids and compounds in the river water that cause the water color is exceeded. Low temperatures, alkalinity and salinity result in the low level of water stability (Langelier index from –3.8 to –1.1 points). Water treatment facilities in Yar-Sale village (WTF-50) do not provide for the standard quality of purified water. This due to both incorrect water treatment technology that involves only filtration for clarification, and an incomplete set of chemicals required to produce drinking water. During the upgrade of the treatment facilities replacing the technology with the traditional clarification flow scheme (sedimentation – filtration) because of the periodic use of high doses of coagulant, as well as supplementing the chemical treatment with processes of alkalization and oxidation of the river water manganese with potassium permanganate was proposed. To assign the design modes of chemical water treatment, in-process tests were carried out under the conditions of the WTF of Yar-Sale village. For clarification and color removal, the chemicals used at the WTF of Yar-Sale village were applied (POHA «Aqua-Aurat-30TM» coagulant, flocculant Praestol 2530). It is shown that using only these chemicals did not provide for the standard quality of drinking water. To enhance the efficiency of purification, it is proposed to carry out chemical treatment in two stages: upstream the sedimentation tanks – alkalization, coagulation and flocculation, then upstream the filters – additional alkalization, oxidation of manganese with potassium permanganate and additional flocculation. The operational doses of chemicals were determined, that ensure the production of stable drinking water meeting the requirements of the current regulatory documents. Based on the test results obtained, a standard operating procedure for designing the upgrade of the WTF-50 of Yar-Sale village was developed.
Key words
deferrization , potassium permanganate , demanganization , river water , stabilization treatment , soda ash , color removal , «Aqua-Aurat-30тм» , Praestol 2530
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DOI 10.35776/MNP.2020.02.01
UDC 628.16.081:542.943-92
Seliukov Aleksandr, Rakhimov V. V.
Reconstruction of the ground water treatment plant
in Noyabrsk (Yamal-Nenets Autonomous Okrug)
Summary
The main results of technological surveys that form the basis for the project of reconstruction of the ground water treatment plant in Noyabrsk (Yamalo-Nenets Autonomous Okrug) are presented. The plant was built according to the project of DAR/VODGEO CJSC (Moscow) and commissioned in September 2006. The plant uses a new technology that provides for the sequential treatment of water with two oxidizing agents – hydrogen peroxide and potassium permanganate to remove iron and manganese compounds. The project shortcomings and incomplete implementation of design solutions complicate the regular operation of the plant and make it difficult to ensure the standard quality of drinking water. It was stated that ground water contained hydrogen sulfide in concentrations up to 0.1 mg/dm3, which required extra consumption of chemicals. Manual dosing of chemicals causes significant deviations from the required doses: from –14.5 to +19.1% for hydrogen peroxide and from –8.5 to +9.1% for potassium permanganate. It is pointed out that crude products of potassium permanganate produced by the P. R. China used as a chemical agent in drinking water supply, pose a threat of increased toxicity of drinking water. The determined value of the Langelier index (index of saturation with calcium carbonate) of ground water (–2.35 units) allowed to conclude that stabilization treatment by alkalization is required. The performed test water treatment with hydrogen peroxide and potassium permanganate in combination with alkalization showed that this process provided for achieving the residual concentrations of manganese < 0.1 mg/dm3 and total iron 0.1–0.15 mg/dm3 in the absence of residual hydrogen sulfide. However, to produce water of constant standard quality, high accuracy of chemical dosing is required that can only be provided by completely automated dosing. The project of upgrading the ground water treatment plant in Noyabrsk designed on the basis of technological research, allows to resolve the existing problems and ensure the standard quality of drinking water.
Ключевые слова
deferrization , ground water , hydrogen peroxide , potassium permanganate , demanganization , stabilization treatment , caustic soda , hydrogen sulfide removal
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UDC 628.16.094.7
Seliukov Aleksandr
Stabilization treatment of underground waters in the Tyumen North Region
Summary
The necessity of stabilization treatment of underground water used for potable water supply of the Tyumen North settlements is substantiated. The expediency of adding alkaline agents in the process of stabilization at the existing water treatment facilities in particular, is shown. Caustic soda is recommended as a stabilization agent. The in-process tests were carried out with water from Novomikhailovsk and Altymsk aquifiers that are most often used for potable water supply in the region.
Key words
iron , manganese , carbon dioxide , cold low-mineralized ground water , stabilization treatment , alkaline agent , caustic soda
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